• Title of article

    Random error bias in principal component analysis. Part II. Application of theoretical predictions to multivariate problems

  • Author/Authors

    N.M. Faber، نويسنده , , MJ Meinders، نويسنده , , P. Geladi، نويسنده , , M. Sj?str?m، نويسنده , , L.M.C. Buydens، نويسنده , , G. Kateman، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1995
  • Pages
    11
  • From page
    273
  • To page
    283
  • Abstract
    In the first part of this paper expressions were derived for the prediction of random error bias in the eigenvalues of principal component analysis (PCA) and the singular values of singular value decomposition (SVD). The main issues of Part I were to investigate the question whether adequate prediction of this bias is possible and to discuss how the validation and evaluation of these predictions could proceed for a specific application in practice. The main issue of this second part is to investigate how random error bias should be taken into account. This question will be treated for a number of seemingly disparate multivariate problems. For example, the construction of confidence intervals for the bias-corrected quantities will be discussed with respect to the estimation of the number of significant principal components. The consequences of random error bias for calibration and prediction with ordinary least squares (OLS), principal component regression (PCR), partial least squares (PLS) and the generalized rank annihilation method (GRAM) will also be outlined. Finally, the derived bias expressions will be compared in detail with the corresponding results for OLS and GRAM.
  • Keywords
    Principal component analysis , Singular value decomposition
  • Journal title
    Analytica Chimica Acta
  • Serial Year
    1995
  • Journal title
    Analytica Chimica Acta
  • Record number

    1022633