Author/Authors :
Yeganeh Faal، Ali نويسنده Department of chemistry, Faculty of sciences, Payam noor university, Iran , , Heidary Shayeste، Tavakol نويسنده aDepartment of chemistry, Faculty of sciences, Payam noor university, Iran , , Bordbar ، Maryam نويسنده Department of Chemistry, University of Qom, Qom, Iran , , Jamalyan ، Bahare نويسنده Department of chemistry, Faculty of sciences, Payam noor university, Iran ,
Abstract :
In this work, acidity constants protonated form of 4.4ʹ-bis astilbene-2,2ʹ-disulfonic-disodium salts (TRIAZ) have been determined spectrophotometrically and spectrofluorimetrically at 25?C and ionic strength of 0.1M KNO3. A program based on MCR-ALS applied for determination of acidity constants. The results show that the peak values of dye are influenced by the presence of anionic, cationic, and nonionic surfactants. The effects of sodium dodecyl sulfate (SDS), Triton X-100 (TX-100) and cetyl trimethyl ammonium bromide (CTAB) as a surface-active agent on the acidic and basic forms, and the spectral properties of dye were studied. Also, we determined the critical micelle concentration (CMC) for these surfactants by spectrophotometric and spectrofluorimetric triazine dye probes. In addition, by using of evolving factor analysis (EFA) and multivariate curve resolution alternative least squares (MCR-ALS) methods, acidity constants were acquired.
