Sorptive storage of natural gas onto dry and wet phillipsite: Study of dynamics, storage and delivery

In this work, storage of methane on phillipsite, a naturally occurring zeolite, was studied on wet and dry basis. The temperature and pressure dynamics were investigated. The temperature gradient due to the adsorption of methane on phillipsite was less than 1 °C indicating higher thermal conductivity of this material. A decreased in temperature resulted in higher adsorption capacity. Storage of methane onto phillipsite can be enhanced by wetting the bed and thus hydrate formation. The time needed to reach equilibrium depends strongly on the water content of the adsorbent. The results revealed that the total delivery capacities for dry and wet phillipsite were 32.5 V/V and 74.13 V/V, respectively. A maximum delivery capacity of 138 V/V was reached using wet phillipsite with 350 g water content. The volumetric delivery capacity results indicated that the steady state delivery is more realistic for adsorptive natural gas (ANG) systems.