Many-particle treatment of nonuniform reacting systems A+B→C and A+B→C+D in liquid solutions Original Research Article

The recently developed method of deriving binary non-Markovian (non-stationary) kinetic equations of reactions in liquid solutions has been applied to irreversible reactions A+B→C and A+B→C+D in spatially nonuniform systems. The method is based on the derivation and subsequent closure of hierarchies for correlation forms. Physically clear kinetic equations for local concentrations of reactants showing that the method can be applied to a wide class of the reacting systems have been obtained in the hydrodynamic approximation.