Author/Authors :
H.-S. Lin، نويسنده , , M.G. Erickson، نويسنده , , Y. Lin، نويسنده , , W.H. Basinger، نويسنده , , W.G. Lawrence، نويسنده , , M.C. Heaven، نويسنده ,
Abstract :
The relaxation dynamics of CN in Ar matrices and clusters (CN-Arn, n ≈ 100) have been examined using time- and wavelength-resolved fluorescence techniques. Transfer between levels of the A 2Π and X 2Σ + states was characterized for matrix-isolated CN. The transfer rate constants were consistent with a mechanism controlled by both the energy spacings between the levels, and the Franck-Condon overlaps.
