Title of article :
The chemiluminescent studies of the orbital aligned Ca(1P1) with CH4−nCln (n = 1, 2, 3, 4) reactions Original Research Article
Author/Authors :
Wensheng Yang، نويسنده , , Guo-wen Ding، نويسنده , , Da-li Xu، نويسنده , , Wei-zhong Sun، نويسنده , , Yue-shu Gu، نويسنده , , Guo-zhong He، نويسنده , , Nan-quan Lou، نويسنده ,
Abstract :
The reactions of atomic p orbital aligned Ca(1P1) with CH4−nCln (n = 1, 2, 3, 4) have been studied by means of laser-induced chemiluminescence in a beam-gas apparatus. The reaction of Ca(1P1) + CH3Cl shows a strong preference for perpendicular p orbital approach to CaCl(A2Π) chemiluminescence product channel. Reactions become less sensitive to Ca(1P1) atomic orbital alignment with increasing n. Results are interpreted in terms of the electron-jump model and the orbital-following model. Absolute chemiluminescence cross-sections and branching ratios are also obtained.
