Correlation for the convective and diffusive evaporation of a sessile drop

A simple correlation is developed to compute the evaporation rates of sessile drops and small puddles which are evaporating under the influences of both diffusion and natural convection of the vapor–air mixture surrounding the drop. The correlation is based on experiments conducted with eight hydrocarbons, which provide a factor of 16.6 variation in volatility as indicated by the equilibrium vapor pressures, a factor of 3.6 variation in molecular mass, and a factor of 2.2 variation in mass diffusivity, and thus the correlation is applicable for liquids having a broad range of properties. The correlation predicts the evaporation rates to within a root-mean-square (RMS) error of 6.5% over the broad range of conditions. Limitations of the correlation are investigated, and when one of the species is excluded, the RMS error is reduced to 4.9%.