Title of article
Tandem Hydroformylation/Aldol Addition of Silyl Enol Ethers Bearing Remote Olefinic Functionalities
Author/Authors
Christoph Hollmann، نويسنده , , Peter Eilbracht، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
8
From page
1685
To page
1692
Abstract
Rhodium(I) complex catalysed hydroformylation of unsaturated silyl enol ethers leads to products of an intramolecular aldol addition in a one-pot procedure. Thus β,γ- or γ,δ-unsaturated silyl enol ethers undergo tandem hydroformylation/Mukaiyama aldol reaction to form cyclic O-silylated aldol adducts with high selectivity and good yields.
Keywords
rhodium catalysis , Aldol reaction , hydroformylation , ring synthesis
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1080646
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