Title of article :
The Phenylthiocyclopropylsilyl Group: a Useful Latent Hydroxy Group
Author/Authors :
Rémy Angelaud، نويسنده , , Yannick Landais، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
The α-dimethyl(1-phenylthio)cyclopropylsilyl group was used as a new masked hydroxy group. Three procedures have been devised to allow the oxidation of this silicon group in the presence of various functionalities. The desired alcohols are obtained in high yields with retention of configuration at the carbon centre.
Keywords :
Oxidation , silicon and compounds , Pummerer reactions , sulfoxides
Journal title :
Tetrahedron
Journal title :
Tetrahedron
