• Title of article

    Studies on Chromium(0)-Mediated Three Component Cycloaddition Reactions

  • Author/Authors

    James H. Rigby، نويسنده , , Charles R. Heap، نويسنده , , Namal C. Warshakoon، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    7
  • From page
    2305
  • To page
    2311
  • Abstract
    A novel chromium(0)-promoted three-component alkyne–triene higher-order cycloaddition process is presented. The transformation features tethered alkynes participating in a tandem [6π+2π], [6π+2π] cycloaddition event with cyclic trienes serving as the third reactant. Isomerically homogeneous products possessing five rings and six stereogenic centers are isolated from this reaction in good to excellent yield.
  • Keywords
    cycloheptatrienes , diynes , chromium and compounds , Cycloadditions
  • Journal title
    Tetrahedron
  • Serial Year
    2000
  • Journal title
    Tetrahedron
  • Record number

    1080708