Title of article :
The Reaction of Triphenylphosphonium or Triphenylarsonium Salts with Aldehyde: Effect of the Counteranion on their Reactivity
Author/Authors :
Yung-Son Hon، نويسنده , , Chia-Fu Lee، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Pages :
10
From page :
7893
To page :
7902
Abstract :
Some acetonyltriphenylphosphonium, methoxycarbonylmethyltriphenylphosphonium salts and their triphenylarsonium analogues could undergo Wittig reaction with aldehyde in good yields. Their reactivity was counteranion-dependent and was arranged in the following order: p-TsO−, Br−≪CF3CO2−≪ClCH2CO2−
Keywords :
counteranion , Wittig reaction , ozonide , triphenylphosphonium ylide , triphenylarsonium ylide , triphenylarsonium salts , triphenylphosphonium salts
Journal title :
Tetrahedron
Serial Year :
2000
Journal title :
Tetrahedron
Record number :
1081297
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