Title of article
Unprecedented Cesium and Potassium Fluorides Catalyzed Trialkylsilylation and Tributylstannylation of Terminal Alkynes with Trifluoromethyl-Trialkylsilanes and -Tributylstannane
Author/Authors
Miyuki Ishizaki، نويسنده , , Osamu Hoshino، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
7
From page
8813
To page
8819
Abstract
Cesium and potassium fluorides promoted trialkylsilylation and tributylstannylation of terminal alkynes with trifluoromethyl-trialkylsilanes and -tributylstannane were found to give 1-silyl- and 1-tributylatannyl-alkynes in high yield. The present reactions are applicable to 1-alkynes having a wide range of functional groups such as acetal, iodo, silyl, amino, amido and carbonyl (except for aldehyde) groups.
Keywords
1-alkyne , tributylstannylation , cesium fluoride , potassium fluoride , trialkylsilylation
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1081395
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