Title of article
Facile and selective cleavage of allyl ethers, amines and esters using polymethylhydrosiloxane–ZnCl2/Pd(PPh3)4
Author/Authors
S Chandrasekhar، نويسنده , , Ch Raji Reddy، نويسنده , , R. Jagadeeshwar Rao، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
3435
To page
3438
Abstract
Allyl deprotection to liberate free hydroxy, amino and acid groups from the corresponding allyl ethers, amines and esters is achieved under mild conditions. The reagent combination employed for this transformation is polymethylhydrosiloxane (PMHS), ZnCl2 and Pd(PPh3)4.
Keywords
Palladium catalysis , Polymethylhydrosiloxane , Zinc chloride , allylic protecting groups
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1081930
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