Title of article :
Facile and selective cleavage of allyl ethers, amines and esters using polymethylhydrosiloxane–ZnCl2/Pd(PPh3)4
Author/Authors :
S Chandrasekhar، نويسنده , , Ch Raji Reddy، نويسنده , , R. Jagadeeshwar Rao، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
Allyl deprotection to liberate free hydroxy, amino and acid groups from the corresponding allyl ethers, amines and esters is achieved under mild conditions. The reagent combination employed for this transformation is polymethylhydrosiloxane (PMHS), ZnCl2 and Pd(PPh3)4.
Keywords :
Palladium catalysis , Polymethylhydrosiloxane , Zinc chloride , allylic protecting groups
Journal title :
Tetrahedron
Journal title :
Tetrahedron
