Title of article :
Nucleophilic displacement of homoallylic tosylates: influence of steric hindrance and conformational rigidity
Author/Authors :
A. Fern?ndez-Mateos، نويسنده , , M. Rentzsch، نويسنده , , L. Rodr??guez S?nchez، نويسنده , , R. Rubio Gonz?lez، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
A comparative study on the nucleophilic displacement of homoallylic tosylates with different degrees of hindrance and rigidity is reported. π Bond participation is favoured by hindrance and rigidity, and also by weak nucleophiles such as water or dimethylformamide.
Keywords :
Nucleophile , hindrance , Tosylate
Journal title :
Tetrahedron
Journal title :
Tetrahedron
