Title of article
A Schmidt route to 1-azabicyclo[x.y.0]alkanes: a comparison of carbocation stabilizing groups
Author/Authors
William H Pearson، نويسنده , , Rajesh Walavalkar، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
9
From page
5081
To page
5089
Abstract
The intramolecular Schmidt reactions of tertiary alkyl, tertiary benzylic, tertiary propargylic, and tertiary allylic carbocations with tethered azides are reported. Using product analysis and deuterium labeling studies, the role of cation rearrangement prior to Schmidt reaction is reported.
Keywords
Schmidt reaction , carbocation , Azide , aminodiazonium ion , indolizidine , quinolizidine
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082104
Link To Document