Title of article
1,3-Dipolar cycloaddition of nitrile oxides with unsymmetrically substituted norbornenes
Author/Authors
Peter Mayo، نويسنده , , Tiffany Hecnar، نويسنده , , William Tam، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
11
From page
5931
To page
5941
Abstract
1,3-Dipolar cycloadditions of nitrile oxides with unsymmetrically substituted norbornenes were investigated. The cycloadditions were found to be completely stereoselective, giving only the exo cycloadducts in moderate to good yields. Regioselectivities in the cycloadditions ranging from 50:50 to 100:0 were observed with various unsymmetrically substituted norbornenes.
Keywords
1 , 3-dipolar cycloadditions , Nitrile oxides , bicyclic alkenes , Regioselectivity , Stereoselectivity , remote substituent effects , norbornenes
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082193
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