Title of article
Remote substituent effects on regioselectivity in the Pauson–Khand reaction of 2-substituted norbornenes
Author/Authors
Peter Mayo، نويسنده , , William Tam، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
10
From page
5943
To page
5952
Abstract
The effect of a remote substituent on the regioselectivity in the Pauson–Khand reaction of 2-substituted norbornenes has been investigated. Moderate level of regioselectivity was observed and the regioselectivity increases as the electron-withdrawing power of the remote substituent increases. exo Substituents at C-2 of norbornenes generally gave a higher regioselectivity than the endo substituents.
Keywords
remote substituent effects , Cycloadditions , Stereoelectronic effects , Regioselectivity , transition metal-catalyzed reactions , norbornenes , Pauson–Khand reaction
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082194
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