Author/Authors :
Vincent Dumontet، نويسنده , , Christiane Gaspard، نويسنده , , Nguyen Van Hung، نويسنده , , Jacques Fahy، نويسنده , , Luba Tchertanov، نويسنده , , Thierry Sévenet، نويسنده , , Françoise Guéritte-Voegelein، نويسنده ,
Abstract :
1-Methyl-3-(o-azidophenyl)quinoline-2-one prepared by cyclization of the corresponding o-vinylsubstituted isocyanate under microwave irradiation is directly converted into cryptotackieine 1 by an intramolecular aza-Wittig reaction with trimethylphosphine; alternatively heating followed by reduction of the resulting indoloquinoline derivative provided cryptosanguinolentine 2.
Keywords :
Nitrogen heterocycles , insertion reaction , Alkaloids , aza-Wittig reaction , Microwave heating
