Title of article
Acetylenic silyl ketone as polysynthetic equivalent of useful building blocks in organic synthesis
Author/Authors
Antonella Capperucci، نويسنده , , Alessandro DeglʹInnocenti، نويسنده , , Paolo Dondoli، نويسنده , , Tiziano Nocentini، نويسنده , , Gianna Reginato، نويسنده , , Alfredo Ricci، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
10
From page
6267
To page
6276
Abstract
Ethynyl silyl ketone 1 proved to be a very efficient Michael acceptor in carbocupration and metallocupration reactions. In particular, when using carbocuprates, a smooth entry to polyenals can be obtained, while, when using metallocuprates, silyl- and stannylpropenoyl silanes may be obtained, very powerful intermediates in organic synthesis.
Keywords
acylsilanes , Cuprates , Michael reactions , polyenes , polyenals
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082232
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