Title of article
Stereoselective synthesis of polyfunctionalised hydroxylated cyclopentanes from dihydroxylated 2-cyclopentenone derivatives
Author/Authors
S Caddick، نويسنده , , S Cheung، نويسنده , , V.E Doyle، نويسنده , , L.M Frost، نويسنده , , M.G Soscia، نويسنده , , V.M Delisser، نويسنده , , M.R.V Williams، نويسنده , , Z.C Etheridge، نويسنده , , S Khan، نويسنده , , P.B Hitchcock، نويسنده , , Garry Pairaudeau، نويسنده , , S Vile، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
9
From page
6295
To page
6303
Abstract
Dihydroxylated cyclopentenones can be readily synthesised via a base mediated isomerisation reaction. These species and their derivatives can be used to provide a wide range of synthetically useful intermediates by participation in a variety of stereoselective transformations. These include: nucleophilic and conjugate addition, intermolecular cycloaddition, intramolecular free-radical cyclisation and palladium mediated coupling reactions.
Keywords
Cyclopentenones , Coupling reactions , Diels–Alder reactions , radical cyclisations , Grignard reactions , Conjugate addition
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082235
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