Title of article :
KF–Al2O3 is an efficient solid support reagent for the acetylation of amines, alcohols, and phenols. Impeding effect of solvent on the reaction rate
Author/Authors :
Veejendra K. Yadav، نويسنده , , K. Ganesh Babu، نويسنده , , Manish Mittal، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
KF–Al2O3 brings about rapid acetylation of a range of amines, alcohols, and phenols with Ac2O/AcCl. Aliphatic alcohols are acetylated chemoselectively in the presence of phenols. 1° alcohols react several times faster than 2° alcohols. 3° alcohols do not react.
Keywords :
KF–Al2O3 , Chemoselectivity , Solvent effect , Acetylation
Journal title :
Tetrahedron
Journal title :
Tetrahedron