Radical homologation of d-gluconic acid: highly diastereoselective synthesis of d-gluco-KDO derivatives
Author/Authors :
Derek H.R Barton، نويسنده , , Mauro V De Almeida، نويسنده , , Wansheng Liu، نويسنده , , Tetsuro Shinada، نويسنده , , Joseph Cs Jaszberenyi، نويسنده , , Hélio F Dos Santos، نويسنده , , Mireille Le Hyaric، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
5
From page :
8767
To page :
8771
Abstract :
d-glucono 1,5-lactone was converted to O-protected d-gluconic acids. The latter were transformed to gluco-KDO derivatives using Barton ester-based radical chemistry with high diastereoselectivity.
