Title of article
Asymmetric hetero-Diels–Alder reactions. Reactions of oxazolo[3,2-c]pyrimidines
Author/Authors
Mark C Elliott، نويسنده , , Elbertus Kruiswijk، نويسنده , , David J Willock، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
8
From page
10139
To page
10146
Abstract
Diastereomerically pure oxazolo[3,2-c]pyrimidines can be readily prepared by the reaction of alkenyloxazolines with isocyanates. The mechanism of this transformation has been investigated computationally. These compounds undergo epimerisation upon prolonged heating, a reaction which is consistent with the proposed stepwise mechanism. Hydrolysis reactions of these compounds have been investigated.
Keywords
asymmetric reactions , pyrimidones , Biginelli reactions , Oxazolines
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082638
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