Title of article
Three-component Heck–Diels–Alder cascade processes involving alkylallenes, aryl iodides and dienophiles
Author/Authors
Stephen Brown، نويسنده , , Ronald Grigg، نويسنده , , Joanne Hinsley، نويسنده , , Stewart Korn، نويسنده , , Visuvanathar Sridharan، نويسنده , , Michael D Uttley، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
9
From page
10347
To page
10355
Abstract
A wide variety of aryl/heteroaryl iodides undergo an intermolecular Heck reaction with alkylallenes to furnish 1,3-dienes. These subsequently react in situ with various dienophiles to give Diels–Alder adducts. The chemistry has been extended to incorporate cyclisation-anion capture methodology and the stereochemistry of the products has been determined.
Keywords
Palladium catalysis , 1 , Diels–Alder , Allenes , 3-dienes
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082664
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