Author/Authors :
Anil Kumar، نويسنده , , Sanjay S Pawar، نويسنده ,
Abstract :
The Diels–Alder reaction of anthracene-9-carbinol with N-ethylmaleimide has been investigated in several aqueous salt solutions of different concentrations. The enhancement in reaction rates in the presence of LiCl, NaCl, KCl, MgCl2, Na2SO4 and Gn2SO4 are attributed to the salting-out effect. On the other hand, LiClO4, NaClO4, GnCl, GnBr, CH3COOGn and GnClO4 inhibit the rate owing to the salting-in effect. The variations in rate data can be explained using the experimental solubility data and computed salting coefficients.
