Title of article
The aqueous salt-promoted Diels–Alder reaction of anthracene-9-carbinol with N-ethylmaleimide
Author/Authors
Anil Kumar، نويسنده , , Sanjay S Pawar، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
5
From page
1745
To page
1749
Abstract
The Diels–Alder reaction of anthracene-9-carbinol with N-ethylmaleimide has been investigated in several aqueous salt solutions of different concentrations. The enhancement in reaction rates in the presence of LiCl, NaCl, KCl, MgCl2, Na2SO4 and Gn2SO4 are attributed to the salting-out effect. On the other hand, LiClO4, NaClO4, GnCl, GnBr, CH3COOGn and GnClO4 inhibit the rate owing to the salting-in effect. The variations in rate data can be explained using the experimental solubility data and computed salting coefficients.
Keywords
salting coefficients , Diels–Alder reaction , anthracene-9-carbinol
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1082855
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