Title of article
Stereoselective synthesis of syn-2,7-disubstituted-4,5-oxepenes
Author/Authors
David D D??az، نويسنده , , Juan M Betancort، نويسنده , , Fernando R.P Cris?stomo، نويسنده , , Tomas Martin، نويسنده , , Victor S. Martin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
7
From page
1913
To page
1919
Abstract
An efficient synthesis of the title compounds as pure enantiomers is reported. The method is based on the intramolecular trapping of a carbocation generated by acid treatment of exo-Co2(CO)6-propargyl alcohols by a stereochemically controlled secondary hydroxy group located in a suitable chain.
Keywords
marine metabolites , Nicholas reaction , oxepenes
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1082869
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