Title of article :
Stereoselective synthesis of syn-2,7-disubstituted-4,5-oxepenes
Author/Authors :
David D D??az، نويسنده , , Juan M Betancort، نويسنده , , Fernando R.P Cris?stomo، نويسنده , , Tomas Martin، نويسنده , , Victor S. Martin، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
An efficient synthesis of the title compounds as pure enantiomers is reported. The method is based on the intramolecular trapping of a carbocation generated by acid treatment of exo-Co2(CO)6-propargyl alcohols by a stereochemically controlled secondary hydroxy group located in a suitable chain.
Keywords :
marine metabolites , Nicholas reaction , oxepenes
Journal title :
Tetrahedron
Journal title :
Tetrahedron
