Title of article
First total synthesis of (±)-AM6898A and (±)-AM6898D
Author/Authors
Yoshio Fukuda، نويسنده , , Yasushi Okamoto، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
9
From page
2513
To page
2521
Abstract
We have established an effective method for the syntheses of (±)-AM6898D and its possible three diastereoisomers via Claisen rearrangement, stereoselective epimerization, and introduction of one isoprene unit by umpolung. Additionally, we have achieved the total synthesis of (±)-AM6898A from the same intermediate, by intramolecular aldol condensation.
Keywords
AM6898A , AM6898D , intramolecular aldol condensation , Claisen rearrangement
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1082919
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