Title of article
Does substituentʹs conformation influence the kinetics of reduction reactions on trans-4-X-decal-1-ones and to what extent?
Author/Authors
Giorgio Di Maio، نويسنده , , Maria Gabriella Mascia، نويسنده , , Elisabetta Vecchi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
6
From page
3313
To page
3318
Abstract
Stereochemistry and relative rates kax and keq of reduction reactions on title compounds have been measured under five different reaction conditions (NaBH4 in i-PrOH, LiBH4 and NaAlH4 in THF and LiAlH4 in THF and in Et2O). Experiments indicate that axial substituents behave as far less electronegative than their equatorial counterpart in reactions at the equatorial side of molecules.
Keywords
reduction reactions , kinetics , substituentsיconformation , trans-4-X-decal-1-ones
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083007
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