• Title of article

    Does substituentʹs conformation influence the kinetics of reduction reactions on trans-4-X-decal-1-ones and to what extent?

  • Author/Authors

    Giorgio Di Maio، نويسنده , , Maria Gabriella Mascia، نويسنده , , Elisabetta Vecchi، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    6
  • From page
    3313
  • To page
    3318
  • Abstract
    Stereochemistry and relative rates kax and keq of reduction reactions on title compounds have been measured under five different reaction conditions (NaBH4 in i-PrOH, LiBH4 and NaAlH4 in THF and LiAlH4 in THF and in Et2O). Experiments indicate that axial substituents behave as far less electronegative than their equatorial counterpart in reactions at the equatorial side of molecules.
  • Keywords
    reduction reactions , kinetics , substituentsיconformation , trans-4-X-decal-1-ones
  • Journal title
    Tetrahedron
  • Serial Year
    2002
  • Journal title
    Tetrahedron
  • Record number

    1083007