Title of article
Copper-catalysed aerobic oxidation of alcohols using fluorous biphasic catalysis
Author/Authors
Gianna Ragagnin، نويسنده , , Bodo Betzemeier، نويسنده , , Silvio Quici، نويسنده , , Paul Knochel، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
7
From page
3985
To page
3991
Abstract
A copper(I) catalysed and TEMPO mediated fluorous biphasic oxidation of primary, secondary, allylic and benzylic alcohols with oxygen in the presence of a bipyridine ligand bearing perfluorinated ponytails is described. High chemoselectivities are observed in the oxidation of substituted cyclohexanols (substituted axial cyclohexanols react 6–8 times faster than the corresponding equatorial cyclohexanols).
Keywords
alcohols oxidation , TEMPO , cyclohexanols , fluorous catalysis , fluorinated copper ligands
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083083
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