Title of article :
Solvolytically DMSO-promoted reactions of 1,1,1-trifluoroethyl chloride (HCFC-133a) or fluoride (HFC-134a) with nucleophiles
Author/Authors :
Kai Wu، نويسنده , , Qing-Yun Chen، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Fluorinated gases HCFC-133a (CF3CH2Cl, bp=6°C) and HFC-134a (CF3CH2F, bp=−27°C) are found highly soluble in DMSO. In their DMSO solutions, oxygen-, nitrogen- and sulfur-nucleophilic reactions may occur in normal glassware rather than in the autoclave.
Keywords :
HCFC-133a (CF3CH2Cl) , DMSO , Solubility , HFC-134a (CF3CH2F)
Journal title :
Tetrahedron
Journal title :
Tetrahedron
