Title of article
Solvolytically DMSO-promoted reactions of 1,1,1-trifluoroethyl chloride (HCFC-133a) or fluoride (HFC-134a) with nucleophiles
Author/Authors
Kai Wu، نويسنده , , Qing-Yun Chen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
8
From page
4077
To page
4084
Abstract
Fluorinated gases HCFC-133a (CF3CH2Cl, bp=6°C) and HFC-134a (CF3CH2F, bp=−27°C) are found highly soluble in DMSO. In their DMSO solutions, oxygen-, nitrogen- and sulfur-nucleophilic reactions may occur in normal glassware rather than in the autoclave.
Keywords
HCFC-133a (CF3CH2Cl) , DMSO , Solubility , HFC-134a (CF3CH2F)
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083096
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