Title of article
Epoxide rearrangements using dilithiated aminoalcohols as chiral bases
Author/Authors
Paul S. Brookes، نويسنده , , David B. Milne، نويسنده , , Patrick J Murphy، نويسنده , , Barbara Spolaore، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
6
From page
4675
To page
4680
Abstract
Dilithiated norephedrine and ephedrine have been utilised in the enantioselective rearrangement of cyclic epoxides to allylic alcohols, with dilithiated norephedrine generally giving the best enantioselectivity. Dilithiated ephedrine offered better levels of substrate conversion, but with lower enantioselectivity.
Keywords
enantiospecificity , rearrangements , Epoxides , Basicity
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083158
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