Title of article :
Stereochemistry of the [2+4] cycloaddition of cyclopentyne
Author/Authors :
John C. Gilbert and Stephen F. Martin، نويسنده , , Duen-Ren Hou، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
The [2+4] cycloaddition of cyclopentyne with a pair of diastereomeric 1,3-dienes is found to occur with high stereoselectivity. The results support the applicability of the principles of orbital symmetry even in the case of this exceedingly reactive dienophile.
Keywords :
Diels–Alder reaction , Stereochemistry , Orbital symmetry , Cyclopentyne
Journal title :
Tetrahedron
Journal title :
Tetrahedron
