Title of article
Zirconium-catalyzed preparation of aluminacyclopentanes and synthesis of five-membered carbo- and heterocycles
Author/Authors
Usein M Dzhemilev، نويسنده , , Askhat G Ibragimov، نويسنده , , Ruslan R Gilyazev، نويسنده , , Leila O Khafizova، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
6
From page
1281
To page
1286
Abstract
Novel ‘one-pot’ catalytic methods for the synthesis of cyclopentanols, tetrahydrothiophenes, silacyclopentanes and phospholanes are based on successive transformations of olefins and organoaluminium compounds (R2AlR′) in the presence of Cp2ZrCl2 catalyst. In situ generated aluminacyclopentanes serve as common intermediates in these processes.
Keywords
Silacyclopentanes , Catalysis , Organoaluminium compounds , olefins , Zr Complexes , Cyclopentanols , Cycloalumination , Tetrahydrothiophenes , Phospholanes
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1084838
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