Title of article :
Reaction pathways of zirconocene-catalyzed silylation of alkenes with chlorosilanes
Author/Authors :
Jun Terao، نويسنده , , Yingshi Jin، نويسنده , , Kazushi Torii، نويسنده , , Nobuaki Kambe، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Reaction pathways as well as stereochemistries and stoichiometries of zirconocene-catalyzed silylation of olefins with chlorosilanes in the presence of nBuMgCl were studied and discussed in detail. Rate determining steps were examined by kinetic studies and labeling experiments.
Keywords :
zirconocene , olefins , Silylation , Grignard reagents , Chlorosilanes
Journal title :
Tetrahedron
Journal title :
Tetrahedron
