Title of article :
Enantioselective spiro ene-carbocyclization of 1,6-enynes catalyzed by tropos rhodium(I) complex with skewphos ligand
Author/Authors :
Koichi Mikami، نويسنده , , Yukinori Yusa، نويسنده , , Manabu Hatano، نويسنده , , Kazuki Wakabayashi، نويسنده , , Kohsuke Aikawa، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
A tropos rhodium(I) complex having skewphos ligand is shown to be a highly enantioselective catalyst for asymmetric ene-type carbocyclization of 1,6-enynes with tri-substituted olefins to control quaternary stereogenic centers or spiro-rings.
Keywords :
Cyclization , Rhodium , Tropos , Asymmetric catalysis
Journal title :
Tetrahedron
Journal title :
Tetrahedron
