Title of article
Substituent effect on the diastereoselectivity in the chelation-controlled radical reactions of γ-(p-substituted-benzyloxy)-α-methylene esters with alkyl iodides
Author/Authors
Tomoko Yajima، نويسنده , , Kyoko Okada، نويسنده , , Hajime Nagano، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
11
From page
5683
To page
5693
Abstract
A pronounced substituent effect on the diastereoselectivity in the chelation controlled radical reactions of ethyl γ-(p-substituted-benzyloxy)-α-methylenecarboxylates with alkyl iodides was observed. The syn-selectivity increased in the order of electron-donating ability NO2
Keywords
radical reaction , 3-asymmetric induction , 1 , Substituent effect , Seven-membered chelation
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1085772
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