Title of article
Allyl protecting group mediated intramolecular aglycon delivery (IAD): synthesis of α-glucofuranosides and β-rhamnopyranosides
Author/Authors
Ian Cumpstey، نويسنده , , Antony J. Fairbanks، نويسنده , , Alison J. Redgrave، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
14
From page
9061
To page
9074
Abstract
The use of allyl protecting group mediated intramolecular aglycon delivery (IAD) as a strategy for intramolecular glycosylation has been extended to allow the stereoselective synthesis of α-glucofuranosides and β-rhamnopyranosides, in a totally stereoselective fashion. The efficiency of intramolecular glycosylation is dependent on the protecting group pattern of the glycosyl donor, and on the steric bulk of the glycosyl acceptor.
Keywords
Carbohydrates , Glycosylation , Stereocontrol , Intramolecular aglycon delivery (IAD) , Thioglycosides
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1087117
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