Title of article
Facile conversion of O-silyl protected sugars into their corresponding formates using POCl3·DMF complex
Author/Authors
Marta M. Andrade، نويسنده , , M. Teresa Barros، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
9
From page
9235
To page
9243
Abstract
The direct O-formylation of two selectively protected sugar derivatives using the Vilsmeier–Haack (V–H) complex POCl3·DMF was studied. Primary O-TBDMS and O-TBDPS ethers of sucrose, the most common disaccharide, underwent regio and chemoselective O-formylation with this formylating agent. This conversion was also studied with a monosaccharide analogue.
Keywords
Carbohydrates , Regio and chemoselective O-formylation , Vilsmeier–Haack (V–H) complex
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1087136
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