Title of article
Reactions of N-sulfenyl-1,2-benzisothiazolin-3-ones with nucleophiles
Author/Authors
Ming Bao، نويسنده , , MASAO SHIMIZU AND MASATOSHI OKUTOMI، نويسنده , , Shigeru Shimada، نويسنده , , Junʹichi Inoue، نويسنده , , Takeo Konakahara، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
8
From page
11359
To page
11366
Abstract
Reactions of N-[2-(alkoxycarbonyl)benzenesulfenyl]-1,2-benzisothiazolin-3-ones () with various nucleophiles were examined. Anions of active methylene compounds attacked the sulfur atoms of the sulfenyl moieties of to afford sulfide compounds, while thiols attacked the sulfur atoms of the benzisothiazolinone moieties of to afford ring-opened products. Grignard reagents attacked both the above sulfur atoms to give ring-opened products along with sulfide compounds.
Keywords
Grignard reagents , Thiols , Substitution reactions , 1 , 2-Benzisothiazolin-3-one , active methylene compounds , Nucleophiles , Ring-opening reactions
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1087350
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