Title of article
First total synthesis of heterocurvistone
Author/Authors
Margarita B Villecco، نويسنده , , César A.N Catal?n، نويسنده , , Pedro Joseph-Nathan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
5
From page
959
To page
963
Abstract
The sesquiterpene ketone (±)-heterocurvistone was synthesized in eight steps and 12% overall yield from known methyl R-(+)-3-(4-methyl-3-cyclohexen-1-yl)-3-butenoate, readily available from R-(+)-limonene. The key synthetic step is an oxymercuration-induced cyclization.
Keywords
Synthesis , heterocurvistone , isoheterocurvistone , heterocurvistol , isoheterocurvistol , sesquicineole derivatives
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087503
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