Title of article
A simple and easy access to 3-N-alkyl-5-vinyloxazolidinones mediated by palladium–phosphine catalysts
Author/Authors
Shinji Tanimori، نويسنده , , Ushio Inaba، نويسنده , , Yoshihiro Kato، نويسنده , , Mitsunori Kirihata، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
7
From page
3745
To page
3751
Abstract
A new entry for the synthesis of 3-alkyl substituted 5-vinyloxazolidin-2-one derivatives from cis-2-butenylene-1,4-dicarbonate and primary amines mediated by palladium–phosphine catalysts is described. The scope and limitation, a plausible mechanism, and an asymmetric version of the reaction are also discussed.
Keywords
tandem allylic substitution , Oxazolidinone , Palladium catalyst , Asymmetric synthesis
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087795
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