Author/Authors :
Alexei Anikin، نويسنده , , Michael Maslov، نويسنده , , Joachim Sieler، نويسنده , , Steffen Blaurock، نويسنده , , Jens Baldamus، نويسنده , , Lothar Hennig، نويسنده , , Matthias Findeisen، نويسنده , , Gerd Reinhardt، نويسنده , , Ramona Oehme، نويسنده , , Peter Welzel، نويسنده ,
Abstract :
1α-Amino-1,6,9-trideoxy forskolin was synthesized starting from drimenal and an isoprenoid C5 unit. A tricyclic labdane with the entire forskolin skeleton was available in only four steps. Bartonʹs nitrite photolysis was applied to functionalize C-1.
Keywords :
diterpenes , labdanes , Sharpless dihydroxylation , nitrite photolysis
