• Title of article

    A comparative study of NMR chemical shifts of sparteine thiolactams and lactams

  • Author/Authors

    Renata Kolanos، نويسنده , , Waleria Wysocka، نويسنده , , Tadeusz Brukwicki، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    7
  • From page
    5531
  • To page
    5537
  • Abstract
    The 13C and 1H NMR spectra of the four possible thiolactams of sparteine () were recorded and the thiolactam group effects were determined. Most of the effects are greater than those of the lactam group in the oxo analogs. A good linear correlation between the 13C chemical shifts of CS and those of CO was found. The effects could help in assignment of the spectra and determination of conformation of thiolactams and related thiocarbonyl compounds.
  • Keywords
    bis-quinolizidine alkaloids , 13C NMR , 1H NMR , conformation , 13C and 1H NMR effects of thiocarbonyl group
  • Journal title
    Tetrahedron
  • Serial Year
    2003
  • Journal title
    Tetrahedron
  • Record number

    1087984