Title of article
A comparative study of NMR chemical shifts of sparteine thiolactams and lactams
Author/Authors
Renata Kolanos، نويسنده , , Waleria Wysocka، نويسنده , , Tadeusz Brukwicki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
7
From page
5531
To page
5537
Abstract
The 13C and 1H NMR spectra of the four possible thiolactams of sparteine () were recorded and the thiolactam group effects were determined. Most of the effects are greater than those of the lactam group in the oxo analogs. A good linear correlation between the 13C chemical shifts of CS and those of CO was found. The effects could help in assignment of the spectra and determination of conformation of thiolactams and related thiocarbonyl compounds.
Keywords
bis-quinolizidine alkaloids , 13C NMR , 1H NMR , conformation , 13C and 1H NMR effects of thiocarbonyl group
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087984
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