Title of article
A diastereoselective total synthesis of the sesquiterpene (±)-mutisianthol
Author/Authors
Helena M.C Ferraz، نويسنده , , Andrea M Aguilar، نويسنده , , Luiz F Silva Jr.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
5
From page
5817
To page
5821
Abstract
The total synthesis of the phenolic sesquiterpene mutisianthol has been accomplished in 12 steps from the readily available 2-methylanisole. The required trans-1,3-disubstituted indan intermediate was obtained through a diastereoselective thallium(III) mediated ring contraction of a 1-methyl-1,2-dihydronaphthalene derivative.
Keywords
Ring contraction , Thallium(III) , indan , Total synthesis
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1088061
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