Title of article
Synthesis and application to asymmetric allylic amination of substituted monodonor diazaphospholidine ligands
Author/Authors
Christopher L. Edwards، نويسنده , , Mark R Shipton، نويسنده , , Nathaniel W Alcock، نويسنده , , Howard Clase، نويسنده , , Martin Wills، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
8
From page
6473
To page
6480
Abstract
The synthesis of a series of substituted monodonor diazaphospholidine ligands is described. A regioselective lithiation process is a key step in one of these syntheses. The compounds are designed to be incorporated into soluble polymer and other solid phase supports. Enantiomeric excesses of up to 88% were observed when these compounds were employed in palladium-catalysed asymmetric amination reactions.
Keywords
Allylic , Substitution , Amination , Catalyst , Asymmetric , Ligand
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1088124
Link To Document