Title of article :
Barbier-type reaction mediated with tin nano-particles in water
Author/Authors :
Zhenggen Zha، نويسنده , , Shu Qiao، نويسنده , , Jiaoyang Jiang، نويسنده , , Yusong Wang، نويسنده , , Qian Miao، نويسنده , , Zhiyong Wang، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
Tin nano-particles are employed in the Barbier-type allylation reaction of carbonyl compounds in water to afford the corresponding homoallylic alcohols in good yields. The in situ generated allylation intermediates, allyltin(II) bromide and diallyltin dibromide, have been directly observed by using 1H NMR. A mechanism is proposed based on this observation.
Keywords :
Nano-particles , TIN , Barbier-type reaction , Water , mechanism
Journal title :
Tetrahedron
Journal title :
Tetrahedron
