Author/Authors :
Masayuki Kirihara، نويسنده , , Hiroko Kakuda، نويسنده , , Motohiro Ichinose، نويسنده , , Yuta Ochiai، نويسنده , , Shinobu Takizawa، نويسنده , , Asuka Mokuya، نويسنده , , Kumiko Okubo، نويسنده , , Akihiko Hatano، نويسنده , , Motoo Shiro، نويسنده ,
Abstract :
Tertiary cyclopropanol compounds react with a catalytic amount of vanadyl acetylacetonate in the presence of oxygen affording β-hydroxyketones and β-diketones. For 3-substituted-bicyclo[4.1.0]alkanols, peroxides are obtained, as are the β-hydroxyketones. Conversely, 2-ethoxycarbonylcyclopropyl silyl ethers produce ethyl γ-oxocarboxylate derivatives given the same reaction conditions.
Keywords :
Fragmentation reactions , Cyclopropanes , Vanadium compounds , Peroxides
