Title of article
Practical and highly stereoselective technology for preparation of enantiopure sulfoxides and sulfinamides utilizing activated and functionally differentiated N-sulfonyl-1,2,3-oxathiazolidine-2-oxide derivatives
Author/Authors
Zhengxu Han، نويسنده , , Dhileepkumar Krishnamurthy، نويسنده , , Paul Grover، نويسنده , , Q. Kevin Fang، نويسنده , , Xiping Su، نويسنده , , H. Scott Wilkinson، نويسنده , , Zhi-Hui Lu، نويسنده , , Daniel Magiera، نويسنده , , Chris H. Senanayake، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
23
From page
6386
To page
6408
Abstract
A simple, general, and practical technology to prepare enantiopure 1,2,3-oxathiazolidine-2-oxide derivatives using chiral aryl N-sulfonyl aminoalcohol derivatives and thionyl chloride is reported. The versatility of these novel chiral building blocks (MIOO and TMPOO), was exemplified by the expedient production of a variety of unique chiral sulfoxides and valuable chiral sulfinamides in excellent yields and enantiopurities.
Keywords
Chiral sulfinamide , 1 , 2 , 3-Oxathiazolidine-2-oxide , chiral sulfoxide
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088854
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