Author/Authors :
Esther Caballero، نويسنده , , Dulce Alonso، نويسنده , , Rafael Pelaez Lamamie de Clairac، نويسنده , , Concepci?n ?lvarez، نويسنده , , Pilar Puebla، نويسنده , , Francisca Sanz، نويسنده , , Manuel Medarde، نويسنده , , Fernando Tomé، نويسنده ,
Abstract :
The reaction of (1Z,3E) and (1E,3E) 4-aryl-1-phthalimido-2-trialkylsiloxy-1,3-butadienes with maleimides and quinones has been studied. The observed exo-stereospecifity can be attributed to the simultaneous presence of the phthalimido and aryl groups, which produce strong hindrance during the endo approach.