Title of article :
Stereoselective synthesis of a 12-acetoxyazadiradione analogue
Author/Authors :
Alfonso Fern?ndez-Mateos، نويسنده , , Gustavo Pascual Coca، نويسنده , , Rosa Rubio Gonz?lez، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
The synthesis of the 12-acetoxy enone related to the limonoid azadiradione has been achieved in 12 steps (16% overall yield) starting from tricyclic diester . The key steps involve intramolecular 1,3-dipolar cycloaddition of a nitrile oxide and a Stille coupling reaction of a vinyl iodide with a stannylfuran.
Keywords :
antifeedant , Azadiradione , 1 , Stille coupling , 3-dipolar cycloaddition , Limonoids
Journal title :
Tetrahedron
Journal title :
Tetrahedron
